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Rotational-translattonal energy exchange in molecule-surface collisions

✍ Scribed by D.E. Fitz; A.O. Bawagan; L.H. Beard; D.J. Kouri; R.B. Gerber

Publisher: Elsevier Science
Year: 1981
Tongue: English
Weight: 423 KB
Volume: 80
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(81)85073-7

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✦ Synopsis

Reported are calculations of rotational energy transfer in collisions of Cl* molecules with a rigid, smooth surface, using both sudden approximations and quasi-classical trajectories. High probabilities are found for very large Ai transitions compared to corresponding gas-phase collisions: thus molecular collisions with walls can be extremely efficient in producing rotational transitions.

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