Rotational structure in the spectra of diatomic molecules
β Scribed by Istvan Kovacs, L. Nemes
- Book ID
- 127461394
- Publisher
- Institute of Physics Publishing
- Year
- 1969
- Tongue
- English
- Weight
- 4 MB
- Category
- Library
- ISBN
- 0852741421
No coin nor oath required. For personal study only.
β¦ Synopsis
Text: English (translation)
π SIMILAR VOLUMES
## Nature of the physical problem This program is concerned with the analysis of the intensity distribution in the rotational structure of the CH(A 2 A-X 2 H) spectrum, produced by dissociative excitation of simple aliphatic hydrocarbons (CH4, C2H2, C2H4, C2H6) by electron impact.
For the vibration-rotational motion of a diatomic molecule, various forms of an effective Hamiltonian which includes the corrections of the Born-Oppenheimer approximation in the form of radial functions are reviewed. A procedure to fit vibration-rotational and pure rotational transitions is proposed
The commutator perturbation method, an algebraic version of the Van Vleck-Primas perturbation method, expressed in terms of ladder operators, has been applied to solving the eigenvalue problem of the Hamiltonian describing the vibrational-rotational motion of a diatomic molecule. The physical model