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Rotational Spectroscopy of Mixtures of Trimethylamine and Fluorine: Identification of the Ion Pair [(CH3)3NF]+ … F− in the Gas Phase

✍ Scribed by Prof. Hannelore I. Bloemink; Stephen A. Cooke; Prof. A. C. Legon; Prof. John H. Holloway

Publisher: John Wiley and Sons
Year: 1997
Tongue: English
Weight: 400 KB
Volume: 36
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.199713401

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✦ Synopsis

Previously only thermolyses at T 2 130'C had been investigated [3a,c].

[S] The spectroscopic characterization of 13 was carried out in an admixture with 7 and 12; the assignments ofthe skeletal atoms were based on the values for the corresponding 1-adamantyl compound, which was isolated in the pure state. 1HNMR(400MHz):5=1.15(~,9H;C(CH,),), l.17(d,4J(PH)=1.6Hz,

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