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Rotational relaxation of ocs in liquid n-alkanes: Relation to hydrodynamic properties of the solvent

✍ Scribed by A.M Goulay-Bize; E. Dervil; J. Vincent-Geisse


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
317 KB
Volume
69
Category
Article
ISSN
0009-2614

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✦ Synopsis


The rotatIona rekatlon tune ',R of OCS ddutcd m the rr-alkanes has been dctermmcd by isotropic Raman and IR studies. The results are mterpreted by means of hydrodynanuc theorlcs. On the other hand. a linear relation between rl R and the mversc of the relatwe free volume of the solvent IS observed_