Rotational predissociation of X…BC van der Waals molecules using a rotation-vibration decoupling scheme.

Vibrational predissociation of highly vi

Vibrational predissociation of highly vibrationally excited van der Waals molecules. A quantum-mechanical distorted-wave treatment for vibration and sudden approximation for rotation

✍ M. Aguado; P. Villarreal; G. Delgado-Barrio; P. Mareca; J.A. Beswick 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 451 KB

In this paper a three-dimensional quantum model to study vibrational predissociation of van der Waals molecules is applied to the +-He complex for very high vibrational (SO 4 ~14 64) of the 12 subunit The vibrations are described in the distorted-wave diabatic approximation while rotations are treat