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Rotational Isomers, Intramolecular Hydrogen Bond, and IR Spectra ofo-Vinylphenol

✍ Scribed by Glazunov, V. P.; Berdyshev, D. V.; Balaneva, N. N.; Radchenko, O. S.; Novikov, V. L.

Book ID: 125362136
Publisher: Springer US
Year: 2014
Tongue: English
Weight: 524 KB
Volume: 81
Category: Article
ISSN: 0021-9037
DOI: 10.1007/s10812-014-9880-2

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## Abstract According to the ^1^H, ^13^C and ^15^N NMR spectroscopic data and DFT calculations, the __E__‐isomer of 1‐vinylpyrrole‐2‐carbaldehyde adopts preferable conformation with the __anti__‐orientation of the vinyl group relative to the carbaldehyde oxime group and with the __syn__‐arrangement