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Rotational Isomerization of Dithienylethenes: A Study on the Mechanism Determining Quantum Yield of Cyclization Reaction

✍ Scribed by Goldberg, Alexander; Murakami, Akinori; Kanda, Katsuya; Kobayashi, Takao; Nakamura, Shinichiro; Uchida, Kingo; Sekiya, Hiroshi; Fukaminato, Tuyoshi; Kawai, Tsuyoshi; Kobatake, Seiya; Irie, Masahiro


Book ID
127119957
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
141 KB
Volume
107
Category
Article
ISSN
1089-5639

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A quantum-mechanical study on the stereo
✍ V. Galasso; N. TrinajstiΔ‡ πŸ“‚ Article πŸ“… 1972 πŸ› Elsevier Science 🌐 French βš– 656 KB

most probable conformational arrangements of isomeric bipyrroks, bifurans, bithiophenes, thienylfurans, and biselenophenes have been investigated using the Extended Hflckel MO approach. The barrier heights between the syn and anti forms decrease sharply on going along the series bifurans bithiophene