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Rotational isomerism: Part III. Ultrasonic relaxation and ring inversion in 4-methyl- and 4-phenyl-1,3-dioxan

โœ Scribed by P.C. Hamblin; R.F.M. White; E. Wyn-Jones


Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
701 KB
Volume
4
Category
Article
ISSN
0022-2860

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โœ D. W. Aksnes; K. Ramstad ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 607 KB

## Abstract ^13^C NMR spinโ€lattice relaxation times (__T__~1~) have been measured as a function of temperature for three 2โ€phenylโ€1,3,2โ€dioxarsolanes. The __T__~1~ data have been interpreted in terms of isotropic overall molecular reorientation, internal rotation about the As๏ฃฟPh bond and internal m