Rotational isomerism and structure of penta-1,4-diene: Raman spectrum and ab initio calculations
β Scribed by Gallinella, Enzo; Cadioli, Beniamino
- Book ID
- 126514555
- Publisher
- The Royal Society of Chemistry
- Year
- 1975
- Weight
- 743 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0300-9238
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π SIMILAR VOLUMES
Formanilide has been investigated by free-jet millimeter-wave absorption spectroscopy. The rotational spectrum of the conformer with the formyl hydrogen anti to the phenyl group has been assigned. Several rotational transitions of the ground state have been measured for both normal and ND isotopic s
Ab initio calculations have been used to determine the structural parameters of both the planar and the orthogorial form of H~BNHz. The BN bond hngths were found to be 1.378 A and 1.469 A, respectively. The arrangement about nitrogen is pyramidal in the orthogonal form, The best estimate of the barr