Selective IR-multiphoton excitation of the hyperspherical modes of an ABA-type model molecule is simulated by the Floquet and by the quasi-resonant-approximation techniques. The results are analogous to selective IR-multiphoton excitation of precessor modes in the Hknon-Heiles model system.
โฆ LIBER โฆ
Rotational heating during IR multiphoton excitation
โ Scribed by Joshua B. Halpern
- Book ID
- 103019983
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 338 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
It is shown that significant rotational heating can accompany the infrared multiphoton excitation of polyatomic molecules. The dynamical effects of this heating on dissociation products are discussed. Results of a simple model are displayed.
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