✦ LIBER ✦
Rotational energy transfer on CO (e 3Σ−,v=1) collision with He: interpretation of the propensity rules
✍ Scribed by Mengtao Sun; Guohe Sha
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 204 KB
- Volume
- 378
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
In our previous experimental study [ Chem. Phys. Lett. 179 (1991) 442], three propensity rules of rotational energy transfer on CO ðe 3 R À ; v ¼ 1Þ collision with He were obtained experimentally. To interpret these propensity rules theoretically, a theoretical model is presented in this Letter, based on the time-dependent first-order Born approximation. Not only three propensity rules, which obtained experimentally, are interpreted theoretically, but also a new propensity, which is not concerned in the experiment, is also derived theoretically.