Rotational energy transfer in hydrogen chloride
β Scribed by L.P. Roodhart; G.H. Wegdam
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 214 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0022-2860
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π SIMILAR VOLUMES
4 quantum mechanical study of collision induced electronic-to-rotational energy transfer !n the fluorine-para-hydrogen system (F + Ha) is reported. The three potential energy surfaces of the system, constrained to lie in a fmed plane, are obtained by the diatomics-in-molecules approach, and close-co
State-to-state energy transfer cross sections for Ax + HF (u = 2,4, and 6; J = 4.6,8, and 10) were computed using quasi-classic31 trajectories. Rotationat energy transfer is invariant with increasing u, but gyration energy transfer is signi&antiy enhanced by increasing J.
We have performed large-scale close coupling calculations of rotational-to-rotational energy transfer in HF-HF collisions for the realistic potential energy surface of Brobjer and Murrell. We employ up to 525 angular terms in the expansion of the potential and up to 440 coupled channels in the rotat