A new computational method to account for the effect of anharmonicities on non-radhtive decay ratesofkge molecules in the statisti~l limit is given by using expansions of the generating functions which have been used successfully 'ffl multiphor;on processes. This method is free from the ambiguity wh
Rotational effects on intramolecular radiationless transitions in a large molecule
β Scribed by Aviv Amirav; Joshua Jortner; M. Terazima; B.C. Lim
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 628 KB
- Volume
- 133
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract Polar molecules in selected quantum states can be guided, decelerated, and trapped using electric fields created by microstructured electrodes on a chip. Herein we explore how transitions between two of these quantum states can be induced while the molecules are on the chip. We use CO (
The fluorescence of three nearly identical donor-bridge-acceptor molecules was studied under jet-cooled conditions. These compounds contain a I-cyanonaphthalene group as an electron acceptor (A) and an aniline derivative as an electron donor (D). Their only difference is in the substituent on the pa
The model of Grabowski et al. has been modified and used to account for the absence of a fluorescence band from the twisted form of molecules with torsional mechanisms. We have measured the ground and excited state spectroscopic properties of rhodamine B dissolved in a series of water-ethanol mixed