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Rotational distribution of recombinatively desorbing H2 from polycrystalline Pd

โœ Scribed by H. Zacharias; R. David


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
347 KB
Volume
115
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


Rotational state dslnbuuons have been determined for hydrogen molecules recombmatively desorblog from a polycrystallme Pd surface by laser-mduced fluorescence A tunable vacuum ullravlolet (WV) laser at X = 106 nm has been used lo excite Ihe hydrogen molecules UI the B'X: (b'= 3.5') + X '1: (v" = 0. J") Lyman band The rotational slate Population titnbutlon shows a non-Bokmann charactenstic ~th an average rotational energy less Lhan the surface temperature


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โœ Xiaotian Gu; Luis A. Muรฑoz; Yasuyuki Ishikawa; Brad R. Weiner ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 643 KB

We employ a semi-empirical model that utilizes a kinematic distribution function to calculate the rotational state population distributions of diatomic photofragments from the photodissociation of isotopically variant triatomic molecules. The numerically evaluated rotational distributions of tbe pho