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Rotational diffusion tensors for non-spherical molecules

✍ Scribed by Donald C. Knauss; Glenn T. Evans; David M. Grant

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
484 KB
Volume
71
Category
Article
ISSN
0009-2614

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✦ Synopsis

Tbc rotatlonal tifuslon tensors of cweral ngld molecules are determmed from the rotational fnctlon tensor. The molecular friction tensor IS modeled as a sum over the translational Stokes law fnctton coefficients of the constituent atoms of the molecule. Agreement of the theory w~tb expenmental rotatIonal tifusion constants and orlentattonal correlatton times Is surpramgly good.

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