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Rotational barriers of benzaldehydes in the framework of the intersecting-state model

โœ Scribed by J. Seita; S.J. Formosinho

Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
280 KB
Volume
44
Category
Article
ISSN
0040-4020

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โœฆ Synopsis

A general intersecting-state model has been applied to the rotational barriers of benzaldehydes. It is found that in the gas phase the transition state bond order, n#, is greater than 1.0. implying a siphoning of electronic density from the oxygen lone pairs into the transition state. In solution such siphoning is hindered

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