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Rotational Analysis of the High-Resolution Infrared Spectra of the ν4 and ν5 Bands of Formyl Chloride

✍ Scribed by J.L. French; D.J. Clouthier; C.P. Chan; E.S.F. Ma; V.W.M. Lai; A.J. Merer; R.H. Judge

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
479 KB
Volume
168
Category
Article
ISSN
0022-2852

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✦ Synopsis

The high-resolution infrared spectra of the low-lying (\nu_{4}) and (\nu_{5}) fundamentals of the transient molecule formyl chloride. HCOCl, are reported. Both type (A / B) hybrid bands have been analyzed in detail, providing rotational assignments for the (\mathrm{HCO}^{35} \mathrm{Cl}) and (\mathrm{HCO}^{37} \mathrm{Cl}) isotopomers. The excited state rotational and centrifugal distortion constants have been determined by fitting assignments over a wide range of (J) and (k_{a}) values. No perturbations were detected in either band. a. 1994 Academic Press. Inc.

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