Rotation about the carbonyl carbon-nitrogen bond in micelles of N-(dodecyloxycarbonyl)sarcosinate
โ Scribed by Gerig, J. T.; Peyton, D. H.; Nicoli, D. F.
- Book ID
- 126396105
- Publisher
- American Chemical Society
- Year
- 1982
- Tongue
- English
- Weight
- 801 KB
- Volume
- 104
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
The substantial effect of polar substituents on barriers to rotation about S-N bonds in substituted arenesulfenamides, X-C6H4SWR8R", has been attributed to (p-d)n conjugation between nitrogen and sulfur.' However, no such effect has been observed on barriers to syn, anti interconversion in N-alkylid
which deserves further cownent. Examination of the data presented by the authors o; the above-mentioned communication indicates that the a have failed to differentiate between two unrelated pheonomena which led them to misleading conclusions. This fact can best be demonstrated by data of our own wh