Rotating frame spin-lattice relaxation through anisotropic chemical shift in polycrystalline UF6
β Scribed by R. Blinc; G. Lahajnar; J. Slivnik
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 332 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
## Abstract The ^13^C offβresonance rotating frame spinβlattice relaxation technique is applicable to the study of protien rotational diffusion behaviour in a variety of experimental situations. The original formalism of James and coβworkers (1978) (__J. Amer. Chem. Soc.__ 100, 3590β3594) was const
Proton spin-lattice relaxation times and \({ }^{13} \mathrm{C}\) chemical shift anisotropy measurements have been made on the complexes pentacarbonyl(methyl)manganese(I) and -rhenium(I), \(\mathrm{CH}_{3} M(\mathrm{CO})_{5}\), \(M=\) \(\mathrm{Mn}, \mathrm{Re})\). The barrier to rotation of the meth