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Rotamers of some radical-ions as evidence by optical and esr spectroscopy

โœ Scribed by Tadamasa Shida; and Takamasa Momose


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
610 KB
Volume
126
Category
Article
ISSN
0022-2860

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Rapid exchange of Ca2+ between the bulk
โœ Jean Noel Gex; Claude Daul; Alex Von Zelewsky ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 201 KB

The rate constant for dissociation of [ Ca(AA-)] +, where (AA-) is the radical anion of ascorbic acid, has been measured by observation of specific line broadening in the ESR spectrum. Its value in DMSO at 298 K is 4.68~ 10' s-'. The mechanism for the line broadening is a combination of a g and a hy