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Room-Temperature Organic-Based Magnet (Tc≈50 °C) Containing Tetracyanobenzene and Hexacarbonylvanadate(−I)

✍ Scribed by Michelle L. Taliaferro; Matthew S. Thorum; Joel S. Miller


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
315 KB
Volume
45
Category
Article
ISSN
0044-8249

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Room-Temperature Organic-Based Magnet (T
✍ Michelle L. Taliaferro; Matthew S. Thorum; Joel S. Miller 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 315 KB

The discovery of the first organic-based magnet, [Fe-(C 5 Me 5 ) 2 ]C + [TCNE]C À (TCNE = tetracyanoethylene), [1] led to the development of several new families of magnetically ordered materials based on unpaired electron spins residing in p orbitals. These include [Mn II (hfac) 2 (NITR)] (hfac = h