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Room Temperature Hydroamination of N-Alkenyl Ureas Catalyzed by a Gold(I) N-Heterocyclic Carbene Complex.

✍ Scribed by Christopher F. Bender; Ross A. Widenhoefer


Publisher
John Wiley and Sons
Year
2007
Weight
36 KB
Volume
38
Category
Article
ISSN
0931-7597

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## Abstract A novel chelated ferrocene‐based planar chiral N‐heterocyclic carbene‐Rh(I) complex was synthesized by a simple method. It was applied to the asymmetric transfer hydrogenation of prochiral ketones. Enantioselectivities of up to 67% ee were observed. Copyright Β© 2009 John Wiley & Sons, L