Room-temperature fluorine-induced decrease in the stability of bromine and iodine intercalated carbon fibers

✍ Scribed by Ching-Cheh Hung

• Publisher: Elsevier Science
• Year: 1995
• Tongue: English
• Volume: 33
• Category: Article
• ISSN: 0008-6223
• DOI: 10.1016/0008-6223(94)00129-n

✦ Synopsis

Upon exposure to room-temperature fluorine, intercalated carbon fibers (containing either bromine alone or iodine and bromine together) become heavier and less stable. For Amoco P-100 graphitized carbon fibers, which were intercalated with 18 wt% bromine, 1 hour of fluorine exposure resulted in a large weight increase but caused only a small decrease in thermal stability. An additional 89 hours of fluorine exposure time resulted in small additional increases in fiber weight, but significant further decreases in fiber thermal stability. Such phenomena of weight increase and stability decrease do not occur if the intercalated fibers are exposed to 250°C fluorine. These observations suggest that, at room temperature, fluorine is absorbed quickly by the intercalated fibers and is intercalated slowly into the fibers. Most of the original intercalates are replaced by fluorine in the process of fluorine intercalation.

In an inert environment, the bromine intercalated fibers are much more thermally stable. After 800°C vacuum heating for 2 weeks, the brominated fibers lost about 45% of their bromine, and their resistivity increased from 64 @Q-cm to a range of 95-170 &cm. This is still much lower than the value of 300 &cm for pristine P-100. For practical purposes, to preserve their thermal stability, brominated fibers need to be protected from exposure to fluorine at room temperature or to any intercalate at a temperature where, upon direct contact with graphite, an intercalation compound can easily be formed.

Kev Words-Deintercalation. brominated carbon fibers, iodinated carbon fibers, fluorine-induced deintercacation, thermal stability, intercalate exchange.