Homepage: www.u-bourgogne.fr/limsag [\*\*] The French Ministry of Research (MENRT) and the CNRS (UMR 5633) are gratefully acknowledged. The authors are also grateful to Dr. Anne Chartogne (EU Mass Spectrometry Technologies Centre, Waters Corporation, Almere, The Netherlands) for accurate mass measur
Room-Temperature Autoconversion of Free-Base Corrole into Free-Base Porphyrin
β Scribed by Claude P. Gros; Jean-Michel Barbe; Enrique Espinosa; Roger Guilard
- Book ID
- 101536721
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 123 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0044-8249
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π SIMILAR VOLUMES
We provide a review on the status of theoretical modeling of tautomerization in free-base porphyrin. We focus our discussion on several aspects, namely: (1) potential surfaces for both the stepwise and concerted mechanisms calculated at different levels of theory, (2) solvent effects and (3) kinetic
The synthesis is described of fixed distance triads consisting of zinc porphyrin (ZP), metal-free porphyrin (HP) and pyromellitimide (I) in which the ZP and HP moieties are bridged by a rigid 4,4'biphenylene spacer and related spacers, being held with dihedral angles defined by the torsional angle (