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Role of the solvent in the reaction of nucleophilic thiylation of conjugated molecules containing a triple bond

✍ Scribed by E. N. Prilezhaeva; G. S. Vasil'ev; V. N. Petrov


Book ID
112435668
Publisher
Springer
Year
1967
Tongue
English
Weight
447 KB
Volume
16
Category
Article
ISSN
1573-9171

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## Abstract A proline‐catalyzed asymmetric Michael addition between ketones and __trans__‐β‐nitrostyrene was studied by using the density‐functional theory with mPW1PW91 and B3LYP functionals. Improved insight into the enantio‐ and diastereoselective formation of γ‐nitroketones/‐aldehydes is obtain