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Role of the planar chirality of imine–phosphine hybrid ligands bearing chromium tricarbonyl in the palladium-catalyzed asymmetric allylic alkylation

✍ Scribed by Hye-Young Jang; Hwimin Seo; Jin Wook Han; Young Keun Chung

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
178 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis

Optically active Cr-complexed imine±phosphine hybrid ligands having only a planar chirality showed excellent enantioselectivity for the palladium-catalyzed allylic alkylation with predictable absolute con®guration.

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