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Role of the C3-substituted derivatives of cinchonidine in the enantioselective hydrogenation of ethyl pyruvate on Pt-alumina catalyst in AcOH

✍ Scribed by Cserényi, Szabolcs ;Bucsi, Imre ;Felföldi, Károly


Publisher
Springer
Year
2006
Tongue
English
Weight
123 KB
Volume
87
Category
Article
ISSN
0133-1736

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New data in the enantioselective hydroge
✍ György Szöllősi; Szabolcs Cserényi; Katalin Balázsik; Ferenc Fülöp; Mihály Bartó 📂 Article 📅 2009 🏛 Elsevier Science 🌐 English ⚖ 746 KB

The origin of rate enhancement in the enantioselective heterogeneous catalytic hydrogenation of ethyl pyruvate on Pt modified with the parent cinchonas, as compared to the unmodified Pt, was studied in a solvent mixture toluene/AcOH 9/1. Hydrogenation experiments were carried out in a continuousflow