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Role of rotation in the kinetics of unimolecular decomposition at high pressures

✍ Scribed by N. M. Kuznetsov


Book ID
112360212
Publisher
Springer
Year
1980
Tongue
English
Weight
601 KB
Volume
15
Category
Article
ISSN
0040-5760

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## Abstract Rate constants are calculated for CH~3~ (+ Ar) ⇄ CH~2~ + H (+ Ar) at the limiting low‐pressure, the limiting high‐pressure, as well as the intermediate fall‐off ranges. The results show that published experimental rate constants for methyl dissociation correspond to the fall‐off region