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Role of Noncovalent Interactions in the Enantioselective Reduction of Aromatic Ketimines with Trichlorosilane.

✍ Scribed by Andrei V. Malkov; Andrea Mariani; Kenneth N. MacDougall; Pavel Kocovsky


Publisher
John Wiley and Sons
Year
2004
Weight
54 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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## Abstract The influence of ethers upon carbenes has been investigated computationally by the B3LYP, MP2, and MPWB1K methods. Ylide formation is only obtained with reactive‐electrophilic carbenes like cyclopentadienylidene, whereas more nucleophilic carbenes like cyclopent‐2‐enylidene associate by