Role of intramolecular vibrational relaxation on electron transfer rates: application to pentaammineruthenium(III) (histidine-33)-ferricytochrome c

✍ Scribed by Karl.F. Freed

• Book ID: 103022510
• Publisher: Elsevier Science
• Year: 1983
• Tongue: English
• Weight: 451 KB
• Volume: 97
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(83)80458-8

✦ Synopsis

The strong analogy berween the theoretical descriptions of non-adiabatic radiationless transitions and radiative den? with those for non-adiabatic electron transfer reactions is used to arse that intramolecular vibrational rel.r__rion cAn lu\e si@icant influence on electron transfer rates in isolated system. This also provides a possible rationale for the obsensd lacli of temperature dependence of the Ru II -Fe111 electron transfer rates in pcntasmmineruthcnium (111) (histidine-33)