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Role of H 2 O in Oxidation of Spent High-Temperature Desulfurization Sorbent Fe 2 O 3 and CuO in the Presence of O 2

✍ Scribed by Sasaoka, Eiji; Hatori, Makoto; Yoshimura, Hiroyuki; Su, Caili; Uddin, Md. Azhar


Book ID
127138535
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
67 KB
Volume
40
Category
Article
ISSN
0888-5885

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The role of Fe(II) species on the oxidat
✍ J.M. Santana-Casiano; M. GonzΓ‘lez-DΓ‘vila; F.J. Millero πŸ“‚ Article πŸ“… 2006 πŸ› Elsevier Science 🌐 English βš– 227 KB

The oxidation of Fe(II) at nanomolar levels with O 2 , H 2 O 2 and their mixtures has been studied and a kinetic model has been applied to describe the experimental results. A first order pH dependence is obtained when the H 2 O 2 controls the oxidation, due to the large contributions of FeOH + and