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Role of defect structure in structural sensitivity of the oxidation reactions catalyzed by dispersed transition metal oxides

โœ Scribed by V.A. Sadykov; S.F. Tikhov; S.V. Tsybulya; G.N. Kryukova; S.A. Veniaminov; V.N. Kolomiichuk; N.N. Bulgakov; E.A. Paukshtis; V.P. Ivanov; S.V. Koshcheev; V.I. Zaikovskii; L.A. Isupova; L.B. Burgina

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
93 KB
Volume
158
Category
Article
ISSN
1381-1169

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The dynamics of the scale-metal interface exhibits an asymmetry in behavior in oxidation and other scaling reactions depending on whether the mechanism is one of cation or anion-diffusion. For the cation case, the growth step is at the free surface and line defects at the metal-scale interface serve