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Role of Crystalline Defects in Electrocatalysis: Mechanism and Kinetics of CO Adlayer Oxidation on Stepped Platinum Electrodes

✍ Scribed by Lebedeva, N. P.; Koper, M. T. M.; Feliu, J. M.; van Santen, R. A.


Book ID
120420786
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
250 KB
Volume
106
Category
Article
ISSN
0022-3654

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The kinetics of the electrochemical oxidation of NO,-ion dissolved in DMSO has been studied on Pt electrodes at temperature ranging from 25 to 44'C, by means of potentiostatic E/Icurves and by relaxation techniques. The oxidation reaction is explained in terms of a consecutive reaction scheme which