Role of charged amino acid side chains in the stability and lipid binding of Manduca sexta apolipophorin III

η5-Pentamethylcyclopentadienyliridium(II

η5-Pentamethylcyclopentadienyliridium(III) and -rhodium(III) Labeling of Amino Acids with Aromatic Side Chains – The Importance of Relativistic Effects for the Stability of Cp*Irııı Sandwich Complexes

✍ Diran Agaid Herebian; Claudia S. Schmidt; William S. Sheldrick; Christoph van Wü 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 225 KB 👁 1 views

η 5 -Pentamethylcyclopentadienyliridium(III) and -rhodiumθ = 12.9°from that of the remaining ring atoms. Facial isomers are present in an effective 1:1 ratio for all tryptophan (III) sandwich complexes of the type [(η 5 -Cp\*)M(η 6 -aa)]-(CF 3 SO 3 ) 2 (M = Ir, Rh; 3-14) containing L-tyrosine, L-try