Role and effect of dopant ion on sorption-induced motion of polypyrrole films

✍ Scribed by Hidenori Okuzaki; Takayoshi Kuwabara; Takamitsu Kondo

• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: English
• Weight: 170 KB
• Volume: 36
• Category: Article
• ISSN: 0887-6266
• DOI: 10.1002/(sici)1099-0488(199810)36:14<2635::aid-polb16>3.0.co;2-c

✦ Synopsis

The sorption-induced bending and recovery motion of PPy films containing different dopant ions have been investigated, and the interaction between water vapor and PPy was studied from sorption isotherms and kinetics. It was found that the PPy/BF 4 film exhibited the most rapid motion, and the initial speeds of bending and recovery motion were 7.9 and 5.9 mm s Ϫ1 , respectively. The linear expansion coefficient of the film increased in order of PPy/DBS, PPy/TsO, PPy/ClO 4 , and PPy/BF 4 , which is consistent with the packing density of the PPy chains ( PPy ). The dual-mode sorption model applied to the isothermal sorption of water vapor to the PPy demonstrated that the Langmuir's capacity constant increased in the same order with the PPy , while the Henry's law constant was nearly constant. The sorption kinetics obeyed Fickian despite the dimensional change of the films, and the PPy/BF 4 film had the largest diffusion coefficient of 3.13 ϫ 10 Ϫ8 cm 2 s Ϫ1 . The experimental results indicated that the kind of dopant ion was crucial to the thermodynamics and kinetics of sorption, and the quick and intensive bending motion of PPy/BF 4 films was attributed to the fast diffusion of water vapor, which caused the large dimensional change of the film.