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Robust Poly(allylamine)-graft-poly(N-isopropylacrylamide) Particles Prepared by Physical Crosslinking with Poly(styrene sulfonate)

✍ Scribed by Bo Chen; Changyou Gao


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
212 KB
Volume
26
Category
Article
ISSN
1022-1336

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✦ Synopsis


Abstract

Summary: Robust thermosensitive PAH‐g‐PNIPAAm/PSS particles were prepared by addition of a poly(allylamine)‐graft‐poly(N‐isopropylacrylamide) particle suspension into poly(styrene sulfonate) solution above the LCST of PAH‐g‐PNIPAAm. Scanning force microscopy revealed stable and well‐separated particles in water at room temperature. The zeta‐potential showed a negative surface charge of the particles. Their thermosensitive behavior was demonstrated by dynamic light scattering. The release of rhodamine 6G loaded particles could respond to the incubation temperature.

Fabrication of thermosensitive and robust particle by suspension of in situ formed PAH‐g‐PNIPAAm particle above the LCST in PSS solution.

imageFabrication of thermosensitive and robust particle by suspension of in situ formed PAH‐g‐PNIPAAm particle above the LCST in PSS solution.


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Polyethylene (PE) film was treated by corona discharge and then grafted with N-isopropylacrylamide(NIPAAm) for modification of the surface. The grafted amount was determined by gravimetry and the surface morphology was observed by using a scanning electron microscope. The surface analysis was carrie