Ring-opening–ring-closing metathesis of bicyclo[2.2.2]octenes: a novel synthesis of decalins and hydrindanes
✍ Scribed by Timothy L Minger; Andrew J Phillips
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- French
- Weight
- 88 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Bicyclo[2.2.2]octenes containing an olefinic side-chain undergo ring-opening-ring-closing metathesis to give decalins and hydrindanes in reasonable yields.
📜 SIMILAR VOLUMES
Abstraet--5,6-Bis(chloromethyl)bicyclo[2.2.1]hepta-2-ene undergoes ring opening metathesis polymerization to give poly{1,4-[2,3-bis(chloromethyl)-cyclopentylene] vinylene}. Initiation with MoCIs/MeaSn derived catalyst gives atactic polymer with predominantly trans vinylenes, whereas initiation with
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