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Ring-Opening Polymerization of γ-Bromo-ε-caprolactone: A Novel Route to Functionalized Aliphatic Polyesters

✍ Scribed by Detrembleur, C.; Mazza, M.; Halleux, O.; Lecomte, Ph.; Mecerreyes, D.; Hedrick, J. L.; Jérôme, R.


Book ID
126888350
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
95 KB
Volume
33
Category
Article
ISSN
0024-9297

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Synthesis and Ring Opening Polymerizatio
✍ Sarah El Habnouni; Vincent Darcos; Jean Coudane 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 190 KB

## Abstract A new functional lactone, __α__‐iodo‐__ε__‐caprolactone (__α__I__ε__CL), was synthesized from __ε__‐caprolactone by anionic activation using a non‐nucleophilic strong base (lithium diisopropylamide) followed by an electrophilic substitution with iodine chloride. Ring‐opening (co)polymer