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Ring-opening polymerization of endo and exo-dicyclopentadiene and their 7,8-dihydro derivatives

โœ Scribed by James G. Hamilton; Kenneth J. Ivin; John J. Rooney


Publisher
Elsevier Science
Year
1986
Weight
528 KB
Volume
36
Category
Article
ISSN
0304-5102

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๐Ÿ“œ SIMILAR VOLUMES


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## Abstract Summary: Norbornenylazlactone (NBAz) was prepared by a Dielsโ€Alder cycloaddition between cyclopentadiene and 2โ€vinylโ€4,4โ€dimethylโ€5โ€oxazolone. The stereoselectivity of this pericyclic reaction was in favour of __endo__ isomers. The ringโ€opening metathesis polymerization (ROMP) of NBAz w

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## Abstract The title monomers 1 and 2 were polymerized by Ruโ€, Irโ€, Moโ€, Wโ€ and Reโ€based metathesis catalysts to yield polymers with __cis__ contents ranging from 10% to at least 90% for 1 and 23โ€“60% for 2. Assignments of the ^13^C NMR spectra were made. No significant headโ€tail bias was observed