## Abstract Summary: Norbornenylazlactone (NBAz) was prepared by a DielsโAlder cycloaddition between cyclopentadiene and 2โvinylโ4,4โdimethylโ5โoxazolone. The stereoselectivity of this pericyclic reaction was in favour of __endo__ isomers. The ringโopening metathesis polymerization (ROMP) of NBAz w
โฆ LIBER โฆ
Ring-opening polymerization of endo and exo-dicyclopentadiene and their 7,8-dihydro derivatives
โ Scribed by James G. Hamilton; Kenneth J. Ivin; John J. Rooney
- Publisher
- Elsevier Science
- Year
- 1986
- Weight
- 528 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0304-5102
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## Abstract The title monomers 1 and 2 were polymerized by Ruโ, Irโ, Moโ, Wโ and Reโbased metathesis catalysts to yield polymers with __cis__ contents ranging from 10% to at least 90% for 1 and 23โ60% for 2. Assignments of the ^13^C NMR spectra were made. No significant headโtail bias was observed