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Ring-opening polymerization of benzocyclopropene: A novel synthesis of poly(methylene-1,2-phenylene)

✍ Scribed by Kwon Taek Lim; Sam Kwon Choi


Book ID
105336311
Publisher
Wiley (John Wiley & Sons)
Year
1986
Tongue
English
Weight
138 KB
Volume
24
Category
Article
ISSN
0887-6258

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## Abstract A new unsaturated bicyclic ether, 2‐methylene‐7‐oxabicyclo[2.2.1]heptane (4) was synthesized by successive Diels‐Alder addition of furan to acrylonitrile, hydrogenation of cyano compound 5, and Hofmann degradation of the quaternary ammonium hydrate 7 derived from the amine 6. Cationic p