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Ring-opening polymerization of 5,6-dihydro-4H-1,3-oxazin-6-ones, six-membered "azlactones", to poly(N-acyl-β-peptides)

✍ Scribed by Kobayashi, Shiro; Tsukamoto, Yoshihisa; Saegusa, Takeo


Book ID
125461264
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
484 KB
Volume
23
Category
Article
ISSN
0024-9297

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ChemInform Abstract: Cycloaddition/Ring
✍ S. KANEMASA; T. YOSHIMIYA; E. WADA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

Cycloaddition/Ring Opening of 3-Unsubstituted Cyclic Nitronates, Isoxazoline and 5,6-Dihydro-4H-1,2-oxazine N-Oxides, as Synthetic Equivalents of Functionalized Nitrile Oxides. -Treatment of 3-halo-1-nitropropane [cf. (I)] with base results in cyclization to a nitronate. Trapping with electron-rich