Ring opening polymerization of 2,5-dihydro-2,5-dimethoxyfuran by electrochemical initiation
✍ Scribed by Çiftçi Hakan; Testereci H. Nur
- Publisher
- Springer
- Year
- 2004
- Tongue
- English
- Weight
- 348 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0170-0839
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Lipase-catalyzed ring-opening bulk polymerizations of 3(S)-isopropylmorpholine-2,5-dione (IPMD) were investigated. Selected commercial lipases were screened as catalysts for IPMD polymerization at 100 8C. Polymerizations catalyzed with lipases PPL, PS, and CR result in IPMD conversions of about 50%,
Ring-opening polymerization of 1,5-dioxepan-2-one initiated by 1,1,6,6tetra-n-butyl-1,6-distanna-2,5,7,10-tetraoxacyclodecane was carried out in chloroform, dichloromethane, or 1,2-dichloroethane. Effects of reaction temperature, solvent, and monomer-to-initiator ratio were investigated. Polymerizat