Enantiomerically pure (1) and rucemic (2) methyl-N-( 1-phenylethyl)-2-azabicycld2.2.1 lhept-5-ene-3-carboxylate were found to undergo ring opening metathesis polymerization reactions employing molybdenum alkylidene initiators of the type Mo(CH-t-Bu)(NArXOR), (Ar = 2,6-C,Ha-i-Pr2; R = C(CH,),; C(CH,)
β¦ LIBER β¦
Ring-opening polymerization of 2-azabicyclo-[2,2,1]-hept-5-en-3-one using metathesis catalysts
β Scribed by Cho, Hyun-Nam ;Choi, Sam-Kwon
- Publisher
- John Wiley and Sons
- Year
- 1985
- Weight
- 330 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0360-6376
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## Abstract The title monomers 1 and 2 were polymerized by Ruβ, Irβ, Moβ, Wβ and Reβbased metathesis catalysts to yield polymers with __cis__ contents ranging from 10% to at least 90% for 1 and 23β60% for 2. Assignments of the ^13^C NMR spectra were made. No significant headβtail bias was observed