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Ring-opening polymerization of 1,2-anhydro-3,4,6-tri-O-benzyl-β-D-mannopyranose and 5,6-anhydro-1,2-O-isopropylidene-α-D-glucofuranose by zinc–methoxypropanol complex catalyst

✍ Scribed by Uryu, Toshiyuki ;Harima, Kazunari ;Tsuruta, Teiji ;Suzuki, Chiaki ;Yoshino, Norio ;Schuerch, Conrad


Publisher
John Wiley and Sons
Year
1984
Weight
232 KB
Volume
22
Category
Article
ISSN
0360-6376

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1,2-Anhydro sugar derivatives are important intermediates for the synthesis of oligosaccharides' and polysaccharides2, and also for chemical modification of monosaccharides3. The synthesis of I,2-anhydro-o-manno-4, -o-gluco-5, and -D-galactopyranose6 derivatives by an intramolecular S,2 reaction of