Ring opening polymerization initiated by methylaluminoxane/AlMe3 complexes
✍ Scribed by Zbigniew Florjańczyk; Andrzej Plichta; Marcin Sobczak
- Book ID
- 108248315
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 451 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0032-3861
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Currently there is considerable interest in the controlled ringopening polymerization (ROP) of lactides (LAs) by welldefined metal initiators because of the biodegradable and biocompatible nature of polylactides (PLAs) and their potentially wide-ranging commercial applications. [1, 2] Particularly i
## Abstract Diphenylzinc, alone or in combination with water and butanone as coinitiators, was used as a polymerization initiator system for a variety of lactones at varying temperatures. The resulting data indicate that the course of the polymerization is greatly influenced by the lactone structur