Ring Opening of the Heterocycle in (60)Fullereno(1,2-d)isoxazole. -N-O bond cleavage of easily available cycloadduct (I) opens a new route to the preparation of isomerically pure fullerol derivatives. -(IRNGARTINGER,
Ring opening of the heterocycle in [60]fullereno[1,2-d]isoxazole
โ Scribed by Hermann Irngartinger; Anton Weber
- Book ID
- 104256709
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 120 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
l-Cyano-2-hydroxy-dihydro[60]fuUerene (2) was synthesized by N-O-bond cleavage of the isoxazoline derivative [60]fullereno[l,2-a']isoxazole (1). The esterificafion of valeric acid with this fullerol produced valeric acid 2-eyano-fulleryl ester (3).
๐ SIMILAR VOLUMES
## Abstract magnified image Five series of new heterocyclic compounds of 1,2,4โtriazole Mannich bases, 1,3,4โoxadiazole Mannich bases, 1,3,4โoxadiazolines, 1,2,4โtriazolo[3,4โ__b__]1,3,4โthiadiazines and 1,2,4โtriazolo[3,4โ__b__]1,3,4โthiadiazoles, in which 1,2,3โtriazolyl and isoxazolyl have been