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Ring-opening metathesis polymerization of norbornene catalyzed by substituted titanocene complexes

✍ Scribed by Yanlong Qian; Danfeng Zhang; Jiling Huang; Haiyan Ma; Albert S.C Chan

Publisher: Elsevier Science
Year: 1998
Tongue: English
Weight: 84 KB
Volume: 133
Category: Article
ISSN: 1381-1169
DOI: 10.1016/s1381-1169(98)00086-7

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## Abstract Ring‐opening metathesis polymerization (ROMP) of norbornene catalyzed by niobium(V) __N__,__N__‐dialkylcarbamates Nb(O~2~CNR~2~)~5~, __R__ = Et (**1**), Me (**2**) was studied in the presence of methylaluminoxane (MAO) as a cocatalyst. These novel catalytic systems resulted very active