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Ring-Opening Metathesis Block Copolymerization of Amino Acid Functionalized Norbornene Monomers. Effects of Solvent and pH on Micelle Formation

โœ Scribed by Sutthasupa, Sutthira; Shiotsuki, Masashi; Matsuoka, Hideki; Masuda, Toshio; Sanda, Fumio


Book ID
125888281
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
938 KB
Volume
43
Category
Article
ISSN
0024-9297

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The synthesis of novel diblock polymers containing both a potential charge transport and a non-linear optic block has been accomplished. The synthesis exploits the living, ring-opening metathesis block copolymerization of two norbornene type monomers, one of which contains an unsubstituted N-carbazo

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โœ Sutthira Sutthasupa; Fumio Sanda; Toshio Masuda ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 179 KB

## Abstract Amino acidโ€derived novel norbornene monomers were synthesized and polymerized with ruthenium catalysts. The polymerization rates were affected by the stereo structure of the monomers; __exo,exo__โ€NBL underwent ROMP faster to give the polymers in higher yields than the __endo,exo__โ€count