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Ring-Opening Copolymerization of ( R )-β-Butyrolactone with Macrolide: A New Series of Poly(Hydroxyalkanoate)s

✍ Scribed by Hori, Yoji; Hongo, Hideyuki; Hagiwara, Toshimitsu


Book ID
126476559
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
52 KB
Volume
32
Category
Article
ISSN
0024-9297

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Immortal ring-opening polymerization of
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The zinc alkoxide complex prepared in situ from the reaction of (BDI)Zn(N(SiMe 3 ) 2 ) is an efficient catalyst for both the solution and bulk ring-opening polymerization (ROP) of racemic-bbutyrolactone (BBL). The controlled ''immortal'' ROP of BBL using the binary catalytic system (BDI)Zn(N(SiMe 3