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Ring-Methyl Activation in Pentamethylcyclopentadienyl Complexes. 3. Synthesis and Reactions of (.eta.4-Tetramethylfulvene)(.eta.5-cyclopentadienyl)rhodium and -iridium

โœ Scribed by Gusev, Oleg V.; Sergeev, Sergei; Saez, Isabel M.; Maitlis, Peter M.

Book ID
126106043
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
907 KB
Volume
13
Category
Article
ISSN
0276-7333

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๐Ÿ“œ SIMILAR VOLUMES

Formation of .eta.1-iminoacyl compounds
Formation of .eta.1-iminoacyl compounds by insertion of isonitriles into pentamethylcyclopentadienyl-tetramethylfulvene compounds of titanium and zirconium. Intramolecular C-H activation of a pentamethylcyclopentadienyl group to give a tridentate ligand with two bridged cyclopentadienyl rings and a titanium-vinyl bond in the bridge. Molecular structure of [cyclic][.eta.5:.eta.1:.eta.5-C5Me4CH2C(NHXyl):CN(Xyl)CH2C5Me4]TiCl and [cyclic]Cp*[.eta.5:.eta.1-C5Me4CH2C(:NXyl)C(:NXyl)]ZrCl (Xyl=2,6-Me2C6H3)
โœ Fandos, Rosa.; Meetsma, Auke.; Teuben, Jan H. ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 916 KB